全文获取类型
收费全文 | 5458篇 |
免费 | 1005篇 |
国内免费 | 611篇 |
专业分类
化学 | 3845篇 |
晶体学 | 51篇 |
力学 | 210篇 |
综合类 | 71篇 |
数学 | 467篇 |
物理学 | 2430篇 |
出版年
2024年 | 5篇 |
2023年 | 119篇 |
2022年 | 118篇 |
2021年 | 156篇 |
2020年 | 210篇 |
2019年 | 203篇 |
2018年 | 192篇 |
2017年 | 146篇 |
2016年 | 264篇 |
2015年 | 266篇 |
2014年 | 266篇 |
2013年 | 366篇 |
2012年 | 518篇 |
2011年 | 598篇 |
2010年 | 357篇 |
2009年 | 355篇 |
2008年 | 386篇 |
2007年 | 324篇 |
2006年 | 292篇 |
2005年 | 234篇 |
2004年 | 213篇 |
2003年 | 137篇 |
2002年 | 165篇 |
2001年 | 126篇 |
2000年 | 128篇 |
1999年 | 116篇 |
1998年 | 107篇 |
1997年 | 112篇 |
1996年 | 86篇 |
1995年 | 79篇 |
1994年 | 67篇 |
1993年 | 75篇 |
1992年 | 43篇 |
1991年 | 65篇 |
1990年 | 47篇 |
1989年 | 36篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 18篇 |
1985年 | 17篇 |
1984年 | 10篇 |
1983年 | 11篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有7074条查询结果,搜索用时 218 毫秒
101.
Inorganic electrides are a novel kind of ionic compounds in which the anions are electrons confined in a complex array of cavities or channels and the cations are nanoscale arrays of alkali metal ions that provide charge balance. In electrides the donated electron behaves like a low-density correlated electron gas, whereby the dimensionality of the electron gas and its electronic and magnetic properties are determined by the topology of the cavities in the host matrix. Unlike traditional electrides, in which alkali cations are encapsulated within an organic cage, inorganic electrides are thermally stable. The current inorganic electrides based on alkali metal loaded zeolites can be designed as useful reduced-dimensionality materials. Inorganic electrides are powerful reducing agents, and they are able to reduce small aromatic molecules to the radical anions within the channels of the zeolite. 相似文献
102.
在线双毛细管-氢化物火焰原子吸收光谱法测定砷、锑、铋、汞、硒和锡 总被引:5,自引:0,他引:5
1引言使用氢化物原子吸收光谱(HG-AAS)法测定As、Sb、B、iHg、Se和Sn已有报道。但将氢化物在线引入空气乙炔焰,用火焰法快速测定这些元素的方法少见报道。本实验利用双毛细管装置,建立了在线HG-AAS测定As、Sb、B、iHg、Se和Sn的方法,该方法具有简便、快速、灵敏度高,干扰少和KBH4用量少的优点。2实验部分2.1仪器及试剂GGX-9型原子吸收分光光度计;微型多功能进样装置(自制专利产品);空心阴极灯;盐酸(1 1);硫脲溶液(5%);抗坏血酸溶液(5%);KBH4溶液(1%,2%);邻二氮菲溶液(1%);As、Sb、B、iHg、Se、Sn的标准溶液;蒸馏水;其余试剂… 相似文献
103.
104.
105.
The chemical adsorption of H atoms on an (8,0) zigzag boron nitride nanotube is studied using the density functional theory with the supercell method. One to four H atoms per 32 B and 32 N are considered. The results show that H atoms prefer to adsorb on the top sites of adjacent B and N atoms to form an armchair chain along the tube axis. An even-odd oscillation behavior of the adsorption energy of H atoms on the tube is found, and the average adsorption energy of even H atoms is obviously bigger than that of odd H atoms. The results can be understood with the frontier orbital theory. Based on this adsorption behavior, several high-symmetric structures of H adsorbed boron nitride nanotubes with 50% and 100% coverages are studied. The pairs of lines' pattern with 50% coverage has the biggest average adsorption energy per H(2) among the chosen configurations, corresponding to approximately 4 wt % hydrogen storage. 相似文献
106.
QuanZhenHUANG GongZhenCHENG HaiBoZHANG SongTaoDING XiaoBingYANG XiaoHaiZHOU GaoYongZHANG 《中国化学快报》2005,16(4):497-500
The Q-band position of tin-centered 5, 9, 14, 18, 23, 27, 32, 36-octabutoxy 2, 3-phthalocyanine(SnNc(OBu)8) exhibits dramatic red-shift as mixed with SnCl2 in CH2Cl2. 相似文献
107.
本文研究在盐酸介质中以三辛胺氮氧化物(分子式为(C_8H)O,简称TOO),萃取金(Ⅲ)的行为及其机理。用等温曲线、斜率、Job法、紫外光谱、摩尔电导、红外和核磁共振等方法确定了萃合物的组成,表明系由两个TOO分子和H~+发生氢键作用,并与AuCl形成离子缔合物,其组成可表述为[TON0…H~+…0NOT]AuCl_4-。 相似文献
108.
A model beta-hairpin dodecapeptide [EFGWVpGKWTIK] was designed by including a favorable D-ProGly Type II' beta-turn sequence and a Trp-zip interaction, while also incorporating a beta-strand unfavorable glycine residue in the N-terminal strand. This peptide is highly folded and monomeric in aqueous solution as determined by combined analysis with circular dichroism and 1H NMR spectroscopy. A peptide representing the folded conformation of the model beta-hairpin [cyclic(EFGWVpGKWTIKpG)] and a linear peptide representing the unfolded conformation [EFGWVPGKWTIK] yield unexpected relative deviations between the CD and 1H NMR spectroscopic results that are attributed to variations in the packing interactions of the aromatic side chains. Mutational analysis of the model beta-hairpin indicates that the Trp-zip interaction favors folding and stability relative to an alternate hydrophobic cluster between Trp and Tyr residues [EFGYVpGKWTIK]. The significance of select diagonal interactions in the model beta-hairpin was tested by rearranging the cross-strand hydrophobic interactions to provide a folded peptide [EWFGIpGKTYWK] displaying evidence of an unusual backbone conformation at the hydrophobic cluster. This unusual conformation does not appear to be a result of the glycine residue in the beta-strand, as replacement with a serine results in a peptide [EWFSIpGKTYWK] with a similar and seemingly characteristic CD spectrum. However, an alternate arrangement of hydrophobic residues with a Trp-zip interaction in a similar position to the parent beta-hairpin [EGFWVpGKWITK] results in a folded beta-hairpin conformation. The differences between side chain packing of these peptides precludes meaningful thermodynamic analysis and illustrates the caution necessary when interpreting beta-hairpin folding thermodynamics that are driven, at least in part, by aromatic cross strand interactions. 相似文献
109.
110.